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M 4 H 4 X: Hydrometals (M=Cu, Ni) Containing Tetracoordinate Planar Nonmetals (X=B, C, N, O)
Author(s) -
Li SiDian,
Ren GuangMing,
Miao ChangQing,
Jin ZhiHao
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200353068
Subject(s) - tetracoordinate , nonmetal , planar , crystallography , ab initio , ab initio quantum chemistry methods , square (algebra) , chemistry , physics , materials science , computer science , mathematics , molecule , geometry , computer graphics (images) , organic chemistry , metal
The first theoretical evidence for tetracoordinate planar nonmetals hosted at the centers of square hydrometal complexes M 4 H 4 X (M=Cu, Ni; X=B, C, N, O; see picture) has been obtained by ab initio calculations. These predictions may open a new branch of chemistry of nonmetal‐centered hydrometals with potential applications as catalysts.
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