Enantiomeric Resolution of a Ruffled Porphyrinoid | Zendy

Daniell Heather W. | Zendy; Brückner Christian | Zendy

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Enantiomeric Resolution of a Ruffled Porphyrinoid

Author(s) -

Daniell Heather W.,

Brückner Christian

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352970

Subject(s) - diastereomer , enantiomer , chemistry , chromophore , conformational isomerism , stereochemistry , linkage (software) , side chain , resolution (logic) , crystallography , organic chemistry , molecule , polymer , biochemistry , computer science , artificial intelligence , gene

Let's twist again : Reaction of a racemic mixture of secochlorinato nickel( ii) with cholesterol generates separable diastereomers of a novel porphyrinic chromophore containing a direct β‐to‐ o ‐phenyl linkage. Exchange of the cholesteryl side chain for an ethyl group produces the enantiomeric conformers of the ruffled macrocycle (see picture).

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