Mixed Transition‐Metal—Lanthanide Complexes at Higher Oxidation States: Heteronuclear Ce IV –Mn IV  Clusters | Zendy

Tasiopoulos Anastasios J. | Zendy; O'Brien Ted A. | Zendy; Abboud Khalil A. | Zendy; Christou George | Zendy

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Mixed Transition‐Metal—Lanthanide Complexes at Higher Oxidation States: Heteronuclear Ce IV –Mn IV Clusters

Author(s) -

Tasiopoulos Anastasios J.,

O'Brien Ted A.,

Abboud Khalil A.,

Christou George

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352898

Subject(s) - heteronuclear molecule , cerium , lanthanide , manganese , antiferromagnetism , transition metal , chemistry , crystallography , ion , inorganic chemistry , cluster (spacecraft) , metal , stereochemistry , catalysis , nuclear magnetic resonance spectroscopy , physics , condensed matter physics , organic chemistry , computer science , programming language

Wheels within wheels : A new family of mixed cerium( IV )–manganese( IV ) clusters has been prepared spanning a range of Ce:Mn ratios from 3:2 to 1:6. The unusual core of the latter CeMn 6 complex is shown (Ce green, Mn blue, O red). All the compounds exhibit antiferromagnetic interactions between their constituent Mn IV ions.

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