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Mixed Transition‐Metal—Lanthanide Complexes at Higher Oxidation States: Heteronuclear Ce IV –Mn IV Clusters
Author(s) -
Tasiopoulos Anastasios J.,
O'Brien Ted A.,
Abboud Khalil A.,
Christou George
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352898
Subject(s) - heteronuclear molecule , cerium , lanthanide , manganese , antiferromagnetism , transition metal , chemistry , crystallography , ion , inorganic chemistry , cluster (spacecraft) , metal , stereochemistry , catalysis , nuclear magnetic resonance spectroscopy , physics , condensed matter physics , organic chemistry , computer science , programming language
Wheels within wheels : A new family of mixed cerium( IV )–manganese( IV ) clusters has been prepared spanning a range of Ce:Mn ratios from 3:2 to 1:6. The unusual core of the latter CeMn 6 complex is shown (Ce green, Mn blue, O red). All the compounds exhibit antiferromagnetic interactions between their constituent Mn IV ions.