Three‐Dimensional Frameworks of Gallium Selenide Supertetrahedral Clusters | Zendy

Bu Xianhui | Zendy; Zheng Nanfeng | Zendy; Wang Xiqing | Zendy; Wang Bing | Zendy; Feng Pingyun | Zendy

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Three‐Dimensional Frameworks of Gallium Selenide Supertetrahedral Clusters

Author(s) -

Bu Xianhui,

Zheng Nanfeng,

Wang Xiqing,

Wang Bing,

Feng Pingyun

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352880

Subject(s) - selenide , gallium , cluster (spacecraft) , conductivity , chemistry , inorganic chemistry , materials science , nanotechnology , selenium , computer science , organic chemistry , computer network

Humidity‐dependent electrical conductivity , which suggests possible applications in sensors, is exhibited by OCF‐6GaSe, an open‐framework gallium selenide assembled from T3 (Ga 10 Se 20 10− ) supertetrahedral clusters (picture, left). Furthermore, materials based on T4 (Zn 4 Ga 16 Se 35 14− , right), the largest supertetrahedral selenide cluster so far, were also obtained.

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