Rational Design of an Enneanuclear Copper( II ) Complex with a Metallacyclophane Core | Zendy

Ottenwaelder Xavier | Zendy; Cano Joan | Zendy; Journaux Yves | Zendy; Rivière Eric | Zendy; Brennan Conor | Zendy; Nierlich Martine | Zendy; RuizGarcía Rafael | Zendy

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Rational Design of an Enneanuclear Copper( II ) Complex with a Metallacyclophane Core

Author(s) -

Ottenwaelder Xavier,

Cano Joan,

Journaux Yves,

Rivière Eric,

Brennan Conor,

Nierlich Martine,

RuizGarcía Rafael

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352851

Subject(s) - denticity , copper , rational design , core (optical fiber) , ferromagnetism , chemistry , crystallography , computer science , physics , materials science , nanotechnology , condensed matter physics , telecommunications , crystal structure , organic chemistry

A hexakis‐bidentate building block : Tricopper( II ) and enneacopper( II ) 1,3,5‐metallacyclophanes were synthesized by a combination of self‐assembly and a rational approach (see scheme). Both complexes exhibit ferromagnetic coupling in the core, through a spin‐polarization mechanism.

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