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Rational Design of an Enneanuclear Copper( II ) Complex with a Metallacyclophane Core
Author(s) -
Ottenwaelder Xavier,
Cano Joan,
Journaux Yves,
Rivière Eric,
Brennan Conor,
Nierlich Martine,
RuizGarcía Rafael
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352851
Subject(s) - denticity , copper , rational design , core (optical fiber) , ferromagnetism , chemistry , crystallography , computer science , physics , materials science , nanotechnology , condensed matter physics , telecommunications , crystal structure , organic chemistry
A hexakis‐bidentate building block : Tricopper( II ) and enneacopper( II ) 1,3,5‐metallacyclophanes were synthesized by a combination of self‐assembly and a rational approach (see scheme). Both complexes exhibit ferromagnetic coupling in the core, through a spin‐polarization mechanism.