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Silica–Water Reaction Media: Its Application to the Formation and Ring Opening of Aziridines
Author(s) -
Minakata Satoshi,
Kano Daisuke,
Oderaotoshi Yoji,
Komatsu Mitsuo
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352842
Subject(s) - aziridine , cyanide , chemistry , ring (chemistry) , azide , chloramine t , polymer chemistry , chemical engineering , organic chemistry , engineering
Olefins can be converted into aziridines by using a chloramine‐T/I 2 system, and silica and water as the reaction medium (see picture). Moreover, the ring‐opening reaction of the resulting aziridine with an azide or a cyanide ion proceeds in the same medium.