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π ‐ Conjugated Oligo‐( p ‐phenylenevinylene) Rosettes and Their Tubular Self‐Assembly
Author(s) -
Jonkheijm Pascal,
Miura Atsushi,
Zdanowska Magdalena,
Hoeben Freek J. M.,
De Feyter Steven,
Schenning Albertus P. H. J.,
De Schryver Frans C.,
Meijer E. W.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352790
Subject(s) - supramolecular chemistry , conjugated system , hydrogen bond , crystallography , self assembly , polymer science , polymer chemistry , chemistry , space (punctuation) , nanotechnology , materials science , computer science , polymer , organic chemistry , molecule , crystal structure , operating system
Hierarchical self‐assembly : Oligo( p ‐phenylenevinylene)s with pendant diamino triazine moieties can self‐assemble through hydrogen‐bonding interactions to give hexameric rosettes (see picture, left). These rosettes further organize into large supramolecular tubules (right) with perfect space filling.