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Stereoselective Construction of Acyclic Carbon Chains by a One‐Pot Coupling Process Based on Alkenyloxazoline–Titanium Complexes
Author(s) -
Mitsui Kazuhisa,
Sato Takayuki,
Urabe Hirokazu,
Sato Fumie
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352769
Subject(s) - stereoselectivity , titanium , coupling (piping) , carbon chain , process (computing) , carbon fibers , chemistry , combinatorial chemistry , materials science , computational chemistry , organic chemistry , computer science , metallurgy , catalysis , composite material , programming language , composite number
A versatile organometallic intermediate , an alkenyloxazoline–titanium complex, has been developed that enables one‐pot multicomponent diastereoselective and asymmetric coupling processes to be achieved in a remarkably efficient manner (see scheme).