A Titanosilicate That Is Structurally Analogous to an MWW‐Type Lamellar Precursor | Zendy

Fan Weibin | Zendy; Wu Peng | Zendy; Namba Seitaro | Zendy; Tatsumi Takashi | Zendy

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A Titanosilicate That Is Structurally Analogous to an MWW‐Type Lamellar Precursor

Author(s) -

Fan Weibin,

Wu Peng,

Namba Seitaro,

Tatsumi Takashi

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352723

Subject(s) - lamellar structure , calcination , zeolite , selectivity , chemistry , phase (matter) , chemical engineering , content (measure theory) , materials science , organic chemistry , crystallography , catalysis , engineering , mathematics , mathematical analysis

With an analogous structure to an MWW lamellar precursor, a titanosilicate (denoted Ti‐YNU‐1) has been developed by using a postsynthetic acid‐treatment and calcination procedure (see scheme). The material behaves as a large‐pore zeolite, showing high activity, selectivity, and stability towards the liquid‐phase epoxidation of bulky cycloalkenes using H 2 O 2 as an oxidant.

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