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Anionic Amido N‐Heterocyclic Carbenes: Synthesis of Covalently Tethered Lanthanide–Carbene Complexes
Author(s) -
Arnold Polly L.,
Mungur Shaheed A.,
Blake Alexander J.,
Wilson Claire
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352710
Subject(s) - carbene , chemistry , samarium , reactivity (psychology) , denticity , lanthanide , transition metal carbene complex , yttrium , ligand (biochemistry) , covalent bond , medicinal chemistry , polymer chemistry , metal , stereochemistry , organic chemistry , catalysis , ion , medicine , oxide , biochemistry , alternative medicine , receptor , pathology
Organolanthanides with amido‐tethered N‐heterocyclic carbenes: a new bidentate ligand that tethers an N‐heterocyclic carbene group to a trivalent lanthanide complex (samarium, depicted, N′′=N(SiMe 3 ) 2 ; or yttrium) affords the first organolanthanide amido–carbene complexes and an opportunity to explore the strength and reactivity of the early metal–N‐heterocyclic carbene fragment.