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Heterobimetallic C 3 Complexes through Silylpropargylidyne Desilylation
Author(s) -
Dewhurst Rian D.,
Hill Anthony F.,
Smith Matthew K.
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352693
Subject(s) - bimetallic strip , carbon chain , chemistry , content (measure theory) , range (aeronautics) , carbon fibers , computer science , stereochemistry , information retrieval , mathematics , organic chemistry , materials science , catalysis , algorithm , composite number , composite material , mathematical analysis
Odd compounds : The study of bimetallic complexes spanned by linear carbon chains was mainly restricted to even‐numbered chains. The fluorodesilylation of silylated propargylidynes now provides a range of C 3 ‐spanned heterobimetallic complexes based on Ru and either Mo or W (e.g. see picture).