Enantioselective Suzuki Reactions: Catalytic Asymmetric Synthesis of Compounds Containing Quaternary Carbon Centers | Zendy

Willis Michael C. | Zendy; Powell Luke H. W. | Zendy; Claverie Christelle K. | Zendy; Watson Simon J. | Zendy

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Enantioselective Suzuki Reactions: Catalytic Asymmetric Synthesis of Compounds Containing Quaternary Carbon Centers

Author(s) -

Willis Michael C.,

Powell Luke H. W.,

Claverie Christelle K.,

Watson Simon J.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352648

Subject(s) - enantioselective synthesis , desymmetrization , chemistry , trifluoromethanesulfonate , catalysis , quaternary carbon , organic chemistry , carbon fibers , combinatorial chemistry , materials science , composite number , composite material

Prochiral ditriflates can act as substrates in asymmetric Suzuki couplings by using an enantioselective desymmetrization strategy. The products are obtained with selectivities up to 86 % ee and contain a quaternary carbon center and a synthetically useful vinyl triflate functionality (see scheme).

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