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Generation of Size‐Controlled Pd 0 Nanoclusters inside Nanoporous Domains of Gel‐Type Resins: Diverse and Convergent Evidence That Supports a Strategy of Template‐Controlled Synthesis
Author(s) -
Corain Benedetto,
Jerabek Karel,
Centomo Paolo,
Canton Patrizia
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352640
Subject(s) - nanoclusters , microporous material , nanoporous , template , size exclusion chromatography , nanotechnology , steric effects , materials science , content (measure theory) , type (biology) , chemical engineering , polymer science , chemistry , mathematics , organic chemistry , geology , composite material , engineering , mathematical analysis , paleontology , enzyme
Resin molds for clusters : The nanoporous domains of a gel‐type microporous functional resin are used as templates for the production of size‐controlled Pd 0 nanoclusters, the size of which is governed by the largest mesh available (see picture). Inverse steric exclusion chromatography provides the quantitative estimate of resin nanoporosity in its swollen state.