Two Unprecedented 3‐Connected Three‐Dimensional Networks of Copper( I ) Triazolates: In Situ Formation of Ligands by Cycloaddition of Nitriles and Ammonia | Zendy

Zhang JiePeng | Zendy; Zheng ShaoLiang | Zendy; Huang XiaoChun | Zendy; Chen XiaoMing | Zendy

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Two Unprecedented 3‐Connected Three‐Dimensional Networks of Copper( I ) Triazolates: In Situ Formation of Ligands by Cycloaddition of Nitriles and Ammonia

Author(s) -

Zhang JiePeng,

Zheng ShaoLiang,

Huang XiaoChun,

Chen XiaoMing

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352627

Subject(s) - cycloaddition , copper , ammonia , trigonal crystal system , hydrothermal circulation , ion , polymer , in situ , chemistry , hydrothermal synthesis , coordination polymer , crystallography , topology (electrical circuits) , combinatorial chemistry , chemical engineering , organic chemistry , crystal structure , catalysis , mathematics , combinatorics , engineering

One‐pot synthesis of 1,2,4‐triazoles : Hydrothermal treatment of copper( II ) ions, ammonia, and nitriles yielded two copper( I ) triazolate coordination polymers, the structures of which have unearthed the unprecedented formation of triazolates through the cycloaddition of NH 3 and RCN. The polymers exhibit novel network topologies based on trigonal nodes (see picture).

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