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Non‐Natural Eight‐Connected Solid‐State Materials: A New Coordination Chemistry
Author(s) -
Long DeLiang,
Hill Robert J.,
Blake Alexander J.,
Champness Neil R.,
Hubberstey Peter,
Proserpio Davide M.,
Wilson Claire,
Schröder Martin
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352625
Subject(s) - lanthanide , solid state , network topology , content (measure theory) , chemistry , computer science , crystallography , organic chemistry , mathematics , computer network , ion , mathematical analysis
Non‐CsCl topologies for eight‐connected solid‐state materials have been observed for the first time in three networks based on lanthanide cations and 4,4′‐bipyridine‐ N , N ′‐dioxide ligands. The structure of the {[Yb(L) 4 ](CF 3 SO 3 ) 3 } ∞ network is depicted.