A Bowl‐Shaped Triarylphosphane with a Large Cone Angle: Synthesis and Crystallographic Analysis of a [(PdX 2 ) 3 (PR 3 ) 2 ]‐Type Complex | Zendy

Ohzu Yoshiko | Zendy; Goto Kei | Zendy; Kawashima Takayuki | Zendy

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A Bowl‐Shaped Triarylphosphane with a Large Cone Angle: Synthesis and Crystallographic Analysis of a [(PdX 2 ) 3 (PR 3 ) 2 ]‐Type Complex

Author(s) -

Ohzu Yoshiko,

Goto Kei,

Kawashima Takayuki

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352616

Subject(s) - trimer , crystallography , palladium , chemistry , structure type , crystal structure , materials science , dimer , catalysis , biochemistry , organic chemistry

A trinuclear palladium( II ) chloride phosphane complex , [(PdCl 2 ) 3 (PAr 3 ) 2 ], is obtained in the reaction of a bowl‐shaped triarylphosphane with a deep cavity with PdCl 2 even when an excess amount of the phosphane is employed. X‐ray crystallography established the structure of the complex: a trimer of PdCl 2 is terminated by two phosphane ligands (see picture).

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