Premium
A Cu II Co II Metallacyclophane‐Based Metamagnet with a Corrugated Brick‐Wall Sheet Architecture
Author(s) -
Pereira Cynthia L. M.,
Pedroso Emerson F.,
Stumpf Humberto O.,
Novak Miguel A.,
Ricard Louis,
RuizGarcía Rafael,
Rivière Eric,
Journaux Yves
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352604
Subject(s) - brickwork , brick , crystallography , moiety , ion , molecule , chemistry , denticity , materials science , stereochemistry , crystal structure , composite material , organic chemistry , engineering , structural engineering
Magnet brickwork: A two‐dimensional molecule‐based metamagnet is obtained by the reaction of Co II ions and the tetra ‐bidentate {Cu 2 (mpba) 2 } 4− moiety. The Co II ions act as cement between {Cu 2 (mpba) 2 } units to form a brick‐wall assembly (see picture). The strong Co II anisotropy and weak interplanar interactions lead to a metamagnetic transition and glassy behavior.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom