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Immobilization of a Metallo Schiff Base into a Microporous Coordination Polymer
Author(s) -
Kitaura Ryo,
Onoyama Goro,
Sakamoto Hirotoshi,
Matsuda Ryotaro,
Noro Sinichiro,
Kitagawa Susumu
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352596
Subject(s) - microporous material , schiff base , polymer , coordination polymer , polymer chemistry , materials science , metal , chemistry , metallurgy , composite material
Wall decoration : Coordinatively unsaturated metal centers (Cu II , Co II , and Ni II ) can be embedded in the pore wall of a microporous coordination polymer containing Schiff base type metalloligands [M(salphdc)] 2− (H 4 salphdc= N , N ′‐ o ‐phenylenebis(salicylideneimine‐5,5′‐dicarboxylic acid)). These coordination polymers possess large 1D channels with dimensions of approximately 14×14 Å 2 (see structure).