Immobilization of a Metallo Schiff Base into a Microporous Coordination Polymer | Zendy

Kitaura Ryo | Zendy; Onoyama Goro | Zendy; Sakamoto Hirotoshi | Zendy; Matsuda Ryotaro | Zendy; Noro Sinichiro | Zendy; Kitagawa Susumu | Zendy

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Immobilization of a Metallo Schiff Base into a Microporous Coordination Polymer

Author(s) -

Kitaura Ryo,

Onoyama Goro,

Sakamoto Hirotoshi,

Matsuda Ryotaro,

Noro Sinichiro,

Kitagawa Susumu

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352596

Subject(s) - microporous material , schiff base , polymer , coordination polymer , polymer chemistry , materials science , metal , chemistry , metallurgy , composite material

Wall decoration : Coordinatively unsaturated metal centers (Cu II , Co II , and Ni II ) can be embedded in the pore wall of a microporous coordination polymer containing Schiff base type metalloligands [M(salphdc)] 2− (H 4 salphdc= N , N ′‐ o ‐phenylenebis(salicylideneimine‐5,5′‐dicarboxylic acid)). These coordination polymers possess large 1D channels with dimensions of approximately 14×14 Å 2 (see structure).

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