Horseshoes, Rings, and Distorted Rings: Studies of Cyclic Chromium‐Fluoride Cages | Zendy

Larsen Finn K. | Zendy; Overgaard Jacob | Zendy; Parsons Simon | Zendy; Rentschler Eva | Zendy; Smith Andrew A. | Zendy; Timco Grigore A. | Zendy; Winpenny Richard E. P. | Zendy

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Horseshoes, Rings, and Distorted Rings: Studies of Cyclic Chromium‐Fluoride Cages

Author(s) -

Larsen Finn K.,

Overgaard Jacob,

Parsons Simon,

Rentschler Eva,

Smith Andrew A.,

Timco Grigore A.,

Winpenny Richard E. P.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352541

Subject(s) - chromium , chemistry , amine gas treating , ammonium , ring (chemistry) , aromaticity , crystallography , molecule , organic chemistry

Running rings around ammonium : Use of amine templates leads to a rich structural chemistry for heterometallic cyclic compounds. For example, use of two diethylammonium cations leads to the formation of the {Cr 10 Cu 2 } cage, which is stabilized by NH⋅⋅⋅F bonds (see picture). The results suggest a new method for making sophisticated polymetallic architectures.

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