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Bispidine Ligand Effects on Iron/Hydrogen Peroxide Chemistry
Author(s) -
Bukowski Michael R.,
Comba Peter,
Limberg Christian,
Merz Michael,
Que Lawrence,
Wistuba Tobias
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352523
Subject(s) - chemistry , hydrogen peroxide , electron paramagnetic resonance , ligand (biochemistry) , stereoselectivity , photochemistry , raman spectroscopy , peroxide , polymer chemistry , heme , inorganic chemistry , catalysis , organic chemistry , nuclear magnetic resonance , biochemistry , physics , receptor , optics , enzyme
. ‥and yet so different. Non‐heme iron complexes catalyze the stereoselective oxidation of CH and CC bonds. Isomeric Fe III ‐ η 1 ‐hydroperoxo and Fe III ‐ η 2 ‐peroxo complexes (see picture), important intermediates in these reactions, were studied by EPR, resonance Raman, and UV/Vis spectroscopies.