Bispidine Ligand Effects on Iron/Hydrogen Peroxide Chemistry | Zendy

Bukowski Michael R. | Zendy; Comba Peter | Zendy; Limberg Christian | Zendy; Merz Michael | Zendy; Que Lawrence | Zendy; Wistuba Tobias | Zendy

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Bispidine Ligand Effects on Iron/Hydrogen Peroxide Chemistry

Author(s) -

Bukowski Michael R.,

Comba Peter,

Limberg Christian,

Merz Michael,

Que Lawrence,

Wistuba Tobias

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352523

Subject(s) - chemistry , hydrogen peroxide , electron paramagnetic resonance , ligand (biochemistry) , stereoselectivity , photochemistry , raman spectroscopy , peroxide , polymer chemistry , heme , inorganic chemistry , catalysis , organic chemistry , nuclear magnetic resonance , biochemistry , physics , receptor , optics , enzyme

. ‥and yet so different. Non‐heme iron complexes catalyze the stereoselective oxidation of CH and CC bonds. Isomeric Fe III ‐ η 1 ‐hydroperoxo and Fe III ‐ η 2 ‐peroxo complexes (see picture), important intermediates in these reactions, were studied by EPR, resonance Raman, and UV/Vis spectroscopies.

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