The Chirality, Porosity, and Ferromagnetism of a 3D Nickel Glutarate with Intersecting 20‐Membered Ring Channels | Zendy

Guillou Nathalie | Zendy; Livage Carine | Zendy; Drillon Marc | Zendy; Férey Gérard | Zendy

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The Chirality, Porosity, and Ferromagnetism of a 3D Nickel Glutarate with Intersecting 20‐Membered Ring Channels

Author(s) -

Guillou Nathalie,

Livage Carine,

Drillon Marc,

Férey Gérard

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352520

Subject(s) - nickel , chirality (physics) , ferromagnetism , porosity , ring (chemistry) , hydrothermal circulation , crystallography , diffraction , dimension (graph theory) , chemistry , materials science , nanotechnology , physics , chemical engineering , condensed matter physics , optics , organic chemistry , combinatorics , mathematics , quantum mechanics , engineering , chiral symmetry breaking , nambu–jona lasinio model , quark

A new dimension to nickel structures : A three‐dimensional nickel glutarate, [Ni 20 {(C 5 H 6 O 4 ) 20 (H 2 O) 8 }]⋅40 H 2 O, has been prepared under hydrothermal conditions. Its structure, solved from X‐ray powder diffraction, is constructed from interconnected 20‐rings, which form a remarkable open network of crossing channels (see picture). It is porous, and exhibits a ferromagnetic long‐range ordering below 4 K.

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