Direct Evidence for Extremely Facile 1,2‐ and 1,3‐Group Migrations in an FeSi 2  System | Zendy

Tobita Hiromi | Zendy; Matsuda Akihisa | Zendy; Hashimoto Hisako | Zendy; Ueno Keiji | Zendy; Ogino Hiroshi | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Direct Evidence for Extremely Facile 1,2‐ and 1,3‐Group Migrations in an FeSi 2 System

Author(s) -

Tobita Hiromi,

Matsuda Akihisa,

Hashimoto Hisako,

Ueno Keiji,

Ogino Hiroshi

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352519

Subject(s) - organosilicon , silylene , silylation , alkyl , aryl , group (periodic table) , chemistry , transition metal , stereochemistry , polymer chemistry , silicon , organic chemistry , catalysis

Facile 1,2‐ and 1,3‐group migrations : The first donor‐free silyl(silylene)–iron complex 1 has been prepared and structurally characterized (see scheme). This complex reacts with t BuNC under mild heating to give a disilanyl complex 2 through 1,3‐alkyl and aryl migration and 1,2‐silyl migration processes. Complex 2 is an example of how organosilicon species bound to transition‐metal centers can change their form in a dynamic fashion (Mes=2,4,6‐trimethylphenyl).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research