A Threefold AlH 2 ‐Coordinated Carbon Atom as Part of the First Carbaalanate | Zendy

Stasch Andreas | Zendy; Roesky Herbert W. | Zendy; von Ragué Schleyer Paul | Zendy; Magull Jörg | Zendy

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A Threefold AlH 2 ‐Coordinated Carbon Atom as Part of the First Carbaalanate

Author(s) -

Stasch Andreas,

Roesky Herbert W.,

von Ragué Schleyer Paul,

Magull Jörg

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352502

Subject(s) - lithium (medication) , ion , chemistry , crystallography , atom (system on chip) , condensation , unit (ring theory) , cluster (spacecraft) , hydride , inorganic chemistry , physics , computer science , computer network , operating system , organic chemistry , hydrogen , thermodynamics , mathematics , psychology , mathematics education , psychiatry

The first carbaalanate consists of a carbaalane dianion [(AlH) 8 (CCH 2 t Bu) 6 ] 2− that is coordinated through hydride bridges to two lithium ions on opposite sides of the cluster (see picture). Additionally, the lithium ions are each further coordinated to a neutral [ t BuCH 2 C(AlH 2 ⋅NMe 3 ) 3 ] unit. In this arrangement, the lithium ion prevents condensation of the [ t BuCH 2 C(AlH 2 ⋅NMe 3 ) 3 ] units.

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