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The Origin of Solvent‐Controlled Supramolecular Chirality Switching in a Bis(Zinc Porphyrin) System
Author(s) -
Borovkov Victor V.,
Hembury Guy A.,
Inoue Yoshihisa
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352493
Subject(s) - enantiopure drug , chirality (physics) , porphyrin , supramolecular chemistry , solvent polarity , supramolecular chirality , zinc , solvent , polarity (international relations) , chemistry , stereochemistry , combinatorial chemistry , crystallography , organic chemistry , crystal structure , enantioselective synthesis , physics , catalysis , chiral symmetry , biochemistry , quantum mechanics , quark , nambu–jona lasinio model , cell
Inducing chirality : The supramolecular interaction of achiral bis(zinc porphyrin) with enantiopure amino acid derivatives in different solvents results in chirality induction. The sign and degree of the circular dichroims is controlled by the solvent polarity (see picture).