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Electron Exchange Along the Tercyclopentadienyltrimetallic Scaffold: Kinetics, Equilibria, and Bond Strengths
Author(s) -
Cammack J. Kevin,
Amouri Hani,
Leonard Philip W.,
Myrabo Randy L.,
Vollhardt K. Peter C.
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352479
Subject(s) - cyclopentadienyl complex , kinetics , metal , displacement (psychology) , chemistry , computational chemistry , materials science , chemical physics , organic chemistry , catalysis , physics , classical mechanics , psychology , psychotherapist
The metallomeric equilibrium between A and B can be quantified kinetically and thermodynamically by direct NMR techniques, which provide an insight into the mechanism of a fundamental organometallic displacement reaction and allows the estimation of relative metal–metal bond strengths in cyclopentadienyl–metal complexes (see scheme).