Gd 5 Si 2 B 8 : A Ternary Rare‐Earth‐Metal Silicide Boride Compound | Zendy

Babizhetskyy Volodymyr | Zendy; Roger Jérome | Zendy; Députier Stéphanie | Zendy; Guérin Roland | Zendy; Jardin Régis | Zendy; Bauer Josef | Zendy; Hiebl Kurt | Zendy; Jardin Christophe | Zendy; Saillard JeanYves | Zendy; Halet JeanFrançois | Zendy

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Gd 5 Si 2 B 8 : A Ternary Rare‐Earth‐Metal Silicide Boride Compound

Author(s) -

Babizhetskyy Volodymyr,

Roger Jérome,

Députier Stéphanie,

Guérin Roland,

Jardin Régis,

Bauer Josef,

Hiebl Kurt,

Jardin Christophe,

Saillard JeanYves,

Halet JeanFrançois

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352468

Subject(s) - boride , ternary operation , silicide , rare earth , boron , materials science , crystallography , metal , ternary compound , silicon , metallurgy , inorganic chemistry , chemistry , organic chemistry , computer science , programming language

Two compounds in one : The boron‐rich ternary compound Gd 5 Si 2 B 8 represents a new structure type containing independent ordered boron and silicon substructures of compositions GdB 4 and Gd 3 Si 2 , respectively, alternating along the c direction (see structure). The compound exhibits metallic character, which is supported by theoretical investigations, and has a rather complex magnetic structure.

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