One‐Dimensional Magnetism in Anhydrous Iron and Cobalt Ternary Oxalates with Rare Trigonal‐Prismatic Metal Coordination Environment | Zendy

Hursthouse Michael B. | Zendy; Light Mark E. | Zendy; Price Daniel J. | Zendy

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One‐Dimensional Magnetism in Anhydrous Iron and Cobalt Ternary Oxalates with Rare Trigonal‐Prismatic Metal Coordination Environment

Author(s) -

Hursthouse Michael B.,

Light Mark E.,

Price Daniel J.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352406

Subject(s) - antiferromagnetism , ternary operation , magnetism , cobalt , coordination complex , crystallography , paramagnetism , metal , chemistry , derivative (finance) , trigonal prismatic molecular geometry , trigonal crystal system , anhydrous , materials science , condensed matter physics , physics , crystal structure , inorganic chemistry , computer science , metallurgy , octahedron , programming language , organic chemistry , economics , financial economics

Imprismed metals : Hydrothermal crystallization of Fe and Co oxalates from extremely concentrated KBr solutions yield a coordination network where the paramagnetic metal ions are in rare coordination geometries (see structure). Both materials show a strong 1D magnetic character and for the Fe II derivative no long‐range order is seen above 2 K, making it a candidate for a Spin 2 quasi‐1D quantum antiferromagnet.

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