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Ion‐Induced Tubular Assembly of Conjugated Schiff‐Base Macrocycles
Author(s) -
Gallant Amanda J.,
MacLachlan Mark J.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352395
Subject(s) - schiff base , supramolecular chemistry , conjugated system , ion , chemistry , base (topology) , supramolecular assembly , combinatorial chemistry , crystallography , polymer chemistry , organic chemistry , polymer , mathematics , crystal structure , mathematical analysis
Ion‐induced assembly : Supramolecular structures are obtained in solution by a new ion‐induced assembly of conjugated Schiff‐base macrocycles. A distinct color change accompanies the aggregation, as shown in the photo. Shown: Macrocycle ( A ); with NaBPh 4 ( B ); with KBPh 4 ( C ); with RbBPh 4 ( D ); with CsBPh 4 ( E ); and with NH 4 BPh 4 ( F ) in CH 2 Cl 2 .