Polymerization by Insertion of Molecular Oxygen into Crystals of 7,7,8,8‐Tetrakis(ethoxycarbonyl)quinodimethane | Zendy

Nomura Shinji | Zendy; Itoh Takahito | Zendy; Ohtake Masaki | Zendy; Uno Takahiro | Zendy; Kubo Masataka | Zendy; Kajiwara Atsushi | Zendy; Sada Kazuki | Zendy; Miyata Mikiji | Zendy

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Polymerization by Insertion of Molecular Oxygen into Crystals of 7,7,8,8‐Tetrakis(ethoxycarbonyl)quinodimethane

Author(s) -

Nomura Shinji,

Itoh Takahito,

Ohtake Masaki,

Uno Takahiro,

Kubo Masataka,

Kajiwara Atsushi,

Sada Kazuki,

Miyata Mikiji

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352355

Subject(s) - copolymer , slipping , polymerization , crystallography , oxygen , crystal structure , materials science , polymer chemistry , oxygen atom , crystal (programming language) , molecular oxygen , chemistry , molecule , polymer , organic chemistry , mechanical engineering , programming language , computer science , engineering

Slipping through the lattice : Molecular oxygen reacts with crystals of quinodimethane 1 to give highly crystalline alternating copolymers by means of a radical mechanism. An X‐ray crystallographic study indicates that the unique arrangement of 1 in the crystal is crucial to the copolymerization.

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