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Cubane {Cu II 4 } Cluster as a Precursor for the Preparation of a Mixed‐Valent {Cu II 12 Cu I 2 } Core
Author(s) -
Mukherjee Arindam,
Nethaji Munirathinam,
Chakravarty Akhil R.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352350
Subject(s) - cubane , cluster (spacecraft) , core (optical fiber) , chemistry , crystallography , materials science , computer science , crystal structure , composite material , programming language
A molecular octopus: A ferromagnetic cubane cluster [{Cu II (HL)} 4 ], which has eight vacant coordination sites on its pendent arms, undergoes metal‐driven self‐assembly to form an antiferromagnetic mixed‐valent tetradecanuclear complex with a prismatic propeller‐shaped {Cu II 12 Cu I 2 } core (see scheme).
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