Ruthenium‐Stabilized Low‐Coordinate Phosphorus Atoms: Structural Evidence for Monomeric Metaphosphonate | Zendy

MenyeBiyogo Richard | Zendy; Delpech Fabien | Zendy; Castel Annie | Zendy; Gornitzka Heinz | Zendy; Rivière Pierre | Zendy

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Ruthenium‐Stabilized Low‐Coordinate Phosphorus Atoms: Structural Evidence for Monomeric Metaphosphonate

Author(s) -

MenyeBiyogo Richard,

Delpech Fabien,

Castel Annie,

Gornitzka Heinz,

Rivière Pierre

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352306

Subject(s) - ruthenium , monomer , moiety , coordination sphere , chemistry , atom (system on chip) , transition metal , phosphorus , crystallography , photochemistry , inorganic chemistry , stereochemistry , crystal structure , organic chemistry , catalysis , computer science , polymer , embedded system

Monomeric metaphosphonate is generated and stabilized within the coordination sphere of a ruthenium atom. The π system of a PO moiety coordinates to the transition metal center and this allows thermodynamic stabilization to give the first structural evidence for monomeric dioxophosphorane.

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