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Ruthenium‐Stabilized Low‐Coordinate Phosphorus Atoms: Structural Evidence for Monomeric Metaphosphonate
Author(s) -
MenyeBiyogo Richard,
Delpech Fabien,
Castel Annie,
Gornitzka Heinz,
Rivière Pierre
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352306
Subject(s) - ruthenium , monomer , moiety , coordination sphere , chemistry , atom (system on chip) , transition metal , phosphorus , crystallography , photochemistry , inorganic chemistry , stereochemistry , crystal structure , organic chemistry , catalysis , computer science , polymer , embedded system
Monomeric metaphosphonate is generated and stabilized within the coordination sphere of a ruthenium atom. The π system of a PO moiety coordinates to the transition metal center and this allows thermodynamic stabilization to give the first structural evidence for monomeric dioxophosphorane.