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[Cp*(η 2 ‐bipy)(MeCN)Ru II ][PF 6 ] Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic [Cp*(η 2 ‐bipy)(η 3 ‐allyl)Ru IV ][PF 6 ] 2 Intermediates
Author(s) -
Mbaye Mbaye D.,
Demerseman Bernard,
Renaud JeanLuc,
Toupet Loïc,
Bruneau Christian
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352257
Subject(s) - allylic rearrangement , regioselectivity , catalysis , chemistry , medicinal chemistry , derivative (finance) , stereochemistry , organic chemistry , financial economics , economics
The coordination of a 2,2′‐bipyridyl derivative to a (C 5 Me 5 )Ru II fragment provides both a facile route to unprecedented dicationic (allyl)Ru IV complexes (see picture) and new highly efficient catalysts for the regioselective allylic substitution from unsymmetrical allylic carbonates.