Mechanism of the Aliphatic Hydroxylation Mediated by a Bis(μ‐oxo)dicopper( III ) Complex | Zendy

Spuhler Philipp | Zendy; Holthausen Max C. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Mechanism of the Aliphatic Hydroxylation Mediated by a Bis(μ‐oxo)dicopper( III ) Complex

Author(s) -

Spuhler Philipp,

Holthausen Max C.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352231

Subject(s) - hydroxylation , reactivity (psychology) , monooxygenase , chemistry , stereochemistry , core (optical fiber) , mechanism (biology) , density functional theory , medicinal chemistry , computational chemistry , enzyme , organic chemistry , cytochrome p450 , computer science , physics , medicine , alternative medicine , pathology , quantum mechanics , telecommunications

The core of the problem : The selective hydroxylation of benzylic CH bonds by a [Cu 2 O 2 ] 2+ core is a nonsynchronous concerted process (see scheme). This is the result of density functional calculations on the mechanistic scenario of the monooxygenase reactivity of a bis(μ‐oxo)dicopper( III ) complex.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research