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A Thiazyl‐Based Organic Ferromagnet
Author(s) -
Alberola Antonio,
Less Robert J.,
Pask Christopher M.,
Rawson Jeremy M.,
Palacio Fernando,
Oliete Patricia,
Paulsen Carley,
Yamaguchi Akira,
Farley Robert D.,
Murphy D. M.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352194
Subject(s) - sulfur , organic molecules , atomic orbital , chemistry , ferromagnetism , diagram , molecule , computer science , organic chemistry , condensed matter physics , physics , database , quantum mechanics , electron
The sulfur–nitrogen radical p ‐O 2 NC 6 F 4 CNSSN . (see packing diagram) provides a rare example of an organic radical that orders ferromagnetically above 1 K. It is suggested that the near orthogonal nature of the singly occupied molecular orbitals of neighboring molecules is important for such behavior to be observed.