Entropy‐Driven Translational Isomerism: A Tristable Molecular Shuttle | Zendy

Bottari Giovanni | Zendy; Dehez Francois | Zendy; Leigh David A. | Zendy; Nash Phillip J. | Zendy; Pérez Emilio M. | Zendy; Wong Jenny K. Y. | Zendy; Zerbetto Francesco | Zendy

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Entropy‐Driven Translational Isomerism: A Tristable Molecular Shuttle

Author(s) -

Bottari Giovanni,

Dehez Francois,

Leigh David A.,

Nash Phillip J.,

Pérez Emilio M.,

Wong Jenny K. Y.,

Zerbetto Francesco

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352176

Subject(s) - isomerization , entropy (arrow of time) , chemistry , computer science , thermodynamics , physics , biochemistry , catalysis

Two's company but three's allowed! An entropy‐driven tristable molecular shuttle has been developed, where shuttling between two of three stations is brought about through a photochemical isomerization, but a further stable co‐conformation is unexpectedly observed simply upon changing the temperature (the picture shows the molecular shuttle in one of the three possible co‐conformations).

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