Conformative Coupling of Two Conformational Molecular Switches | Zendy

Karle Michael | Zendy; Bockelmann Dirk | Zendy; Schumann Dirk | Zendy; Griesinger Christian | Zendy; Koert Ulrich | Zendy

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Conformative Coupling of Two Conformational Molecular Switches

Author(s) -

Karle Michael,

Bockelmann Dirk,

Schumann Dirk,

Griesinger Christian,

Koert Ulrich

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352130

Subject(s) - decalin , ring (chemistry) , unit (ring theory) , coupling (piping) , crystallography , molecule , flip flop , chemistry , stereochemistry , materials science , optoelectronics , psychology , organic chemistry , mathematics education , metallurgy , catalysis , cmos

Passing on information . Two conformational switches, decalin units, were coupled to a 14‐membered bislactam ring (see formula, TBDPS= tert ‐butyldiphenylsilyl). Removal of a bisacetal clamp on the left side of the molecule resulted in a double ring‐flip of the left decalin unit. Conformational coupling through the bislactam unit led to a double ring‐flip in the right decalin unit.

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