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Remote Substituents Controlling Catalytic Polymerization by Very Active and Robust Neutral Nickel( II ) Complexes
Author(s) -
Zuideveld Martin A.,
Wehrmann Peter,
Röhr Caroline,
Mecking Stefan
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200352062
Subject(s) - catalysis , nickel , polymerization , ethylene , chemistry , combinatorial chemistry , polymer chemistry , computer science , organic chemistry , polymer
Remote control : Substituents strongly affect the catalytic properties of complexes 1 in ethylene polymerization, despite their remoteness from the active center. An appropriate substitution pattern provides very active and robust catalysts.