Investigation of Reactive Intermediates of Chemical Reactions in Solution by Electrospray Ionization Mass Spectrometry: Radical Cation Chain Reactions | Zendy

Meyer Sven | Zendy; Koch Rainer | Zendy; Metzger Jürgen O. | Zendy

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Investigation of Reactive Intermediates of Chemical Reactions in Solution by Electrospray Ionization Mass Spectrometry: Radical Cation Chain Reactions

Author(s) -

Meyer Sven,

Koch Rainer,

Metzger Jürgen O.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200352044

Subject(s) - chemistry , mass spectrometry , radical , electrospray ionization , microreactor , photochemistry , electrospray , ionization , extractive electrospray ionization , analytical chemistry (journal) , sample preparation in mass spectrometry , ion , chromatography , organic chemistry , catalysis

Transient radicals tracked down: An electrospray ionization mass spectrometer coupled on‐line to a microreactor system is useful for investigating reactions in solution and for directly detecting reactive intermediates. The transient radical cations 1 .+ and 2 .+ formed in the radical cation chain dimerization of trans ‐anethole were detected unambiguously by MS/MS methods.

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