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Structure and Magnetic Properties of a Chiral Two‐Dimensional Ferrimagnet with T C of 38 K
Author(s) -
Inoue Katsuya,
Kikuchi Koichi,
Ohba Masaaki,
Ōkawa Hisashi
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351888
Subject(s) - ferrimagnetism , ion , chemistry , crystallography , condensed matter physics , materials science , physics , magnetization , magnetic field , organic chemistry , quantum mechanics
Large single crystals of the chiral ferrimagnet [{Cr(CN) 6 }{Mn( S )‐pnH(H 2 O)}](H 2 O) can be recovered from the reaction between K 3 [Cr(CN) 6 ], Mn(ClO 4 ) 2 , and ( S )‐1,2‐diaminopropane dihydrochloride (see picture). Magnetic measurements of the complex show that Mn II and Cr III ions interact ferrimagnetically, with a magnetic transition occurring at 38 K.