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Dicyanocarbodiimide and Trinitreno‐ s ‐triazine Generated by Consecutive Photolysis of Triazido‐ s ‐triazine in a Low‐Temperature Nitrogen Matrix
Author(s) -
Sato Tadatake,
Narazaki Aiko,
Kawaguchi Yoshizo,
Niino Hiroyuki,
Bucher Götz
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351879
Subject(s) - triazine , photodissociation , nitrogen , chemistry , matrix (chemical analysis) , carbon fibers , carbon nitride , molecule , photochemistry , computer science , organic chemistry , catalysis , algorithm , chromatography , photocatalysis , composite number
Carbon nitride molecules: Photolysis ( λ =266 nm) of triazido‐ s ‐triazine (C 3 N 12 , 1 ) in a nitrogen matrix at 20 K yielded a succession of reactive species (see scheme), including, in order, an apparent trinitrene, NCN, and a novel C 3 N 4 isomer, dicyanocarbodiimide NCNCNCN.