Dicyanocarbodiimide and Trinitreno‐ s ‐triazine Generated by Consecutive Photolysis of Triazido‐ s ‐triazine in a Low‐Temperature Nitrogen Matrix | Zendy

Sato Tadatake | Zendy; Narazaki Aiko | Zendy; Kawaguchi Yoshizo | Zendy; Niino Hiroyuki | Zendy; Bucher Götz | Zendy

Premium

Dicyanocarbodiimide and Trinitreno‐ s ‐triazine Generated by Consecutive Photolysis of Triazido‐ s ‐triazine in a Low‐Temperature Nitrogen Matrix

Author(s) -

Sato Tadatake,

Narazaki Aiko,

Kawaguchi Yoshizo,

Niino Hiroyuki,

Bucher Götz

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351879

Subject(s) - triazine , photodissociation , nitrogen , chemistry , matrix (chemical analysis) , carbon fibers , carbon nitride , molecule , photochemistry , computer science , organic chemistry , catalysis , algorithm , chromatography , photocatalysis , composite number

Carbon nitride molecules: Photolysis ( λ =266 nm) of triazido‐ s ‐triazine (C 3 N 12 , 1 ) in a nitrogen matrix at 20 K yielded a succession of reactive species (see scheme), including, in order, an apparent trinitrene, NCN, and a novel C 3 N 4 isomer, dicyanocarbodiimide NCNCNCN.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research