Crystalline‐State Reaction with Allosteric Effect in Spin‐Crossover, Interpenetrated Networks with Magnetic and Optical Bistability | Zendy

Niel Virginie | Zendy; Thompson Amber L. | Zendy; Muñoz M. Carmen | Zendy; Galet Ana | Zendy; Goeta Andrés E. | Zendy; Real José A. | Zendy

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Crystalline‐State Reaction with Allosteric Effect in Spin‐Crossover, Interpenetrated Networks with Magnetic and Optical Bistability

Author(s) -

Niel Virginie,

Thompson Amber L.,

Muñoz M. Carmen,

Galet Ana,

Goeta Andrés E.,

Real José A.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351853

Subject(s) - spin crossover , bistability , allosteric regulation , crystallinity , ligand (biochemistry) , spin transition , crystallography , materials science , spin states , chemistry , transformation (genetics) , condensed matter physics , chemical physics , inorganic chemistry , optoelectronics , physics , organic chemistry , gene , enzyme , biochemistry , receptor

A net change: A fully reversible ligand substitution involving coordination/uncoordination of gaseous water and pyrimidine induces the repetitive allosteric transformation of three interpenetrated nets into a single three‐dimensional net. The transformation does not affect the crystallinity of the sample but alters significantly the spin‐crossover transition; the compound shows magnetic and chromatic bistability (see picture).

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