Ordering Phenomena and Phase Transitions in a Spin‐Crossover Compound—Uncovering the Nature of the Intermediate Phase of [Fe(2‐pic) 3 ]Cl 2 ⋅EtOH | Zendy

Chernyshov Dmitry | Zendy; Hostettler Marc | Zendy; Törnroos Karl W. | Zendy; Bürgi HansBeat | Zendy

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Ordering Phenomena and Phase Transitions in a Spin‐Crossover Compound—Uncovering the Nature of the Intermediate Phase of [Fe(2‐pic) 3 ]Cl 2 ⋅EtOH

Author(s) -

Chernyshov Dmitry,

Hostettler Marc,

Törnroos Karl W.,

Bürgi HansBeat

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351834

Subject(s) - spin crossover , phase (matter) , order (exchange) , spin (aerodynamics) , crossover , chemistry , crystallography , content (measure theory) , condensed matter physics , physics , thermodynamics , computer science , mathematics , organic chemistry , finance , economics , mathematical analysis , artificial intelligence

From disorder to order and back: Contrary to all earlier studies on [Fe(2‐pic) 3 ]Cl 2 ⋅EtOH (pic=picolylamine), an ordered phase (IP) with two crystallographically different iron sites was found between disordered high‐spin (HS) and low‐spin (LS) phases. The picture shows the average FeN distances of all three phases.

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