Transformation of a Spherical Supramolecular Dendrimer into a Pyramidal Columnar Supramolecular Dendrimer Mediated by the Fluorophobic Effect | Zendy

Percec Virgil | Zendy; Glodde Martin | Zendy; Johansson Gary | Zendy; Balagurusamy Venkatachalapathy S. K. | Zendy; Heiney Paul A. | Zendy

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Transformation of a Spherical Supramolecular Dendrimer into a Pyramidal Columnar Supramolecular Dendrimer Mediated by the Fluorophobic Effect

Author(s) -

Percec Virgil,

Glodde Martin,

Johansson Gary,

Balagurusamy Venkatachalapathy S. K.,

Heiney Paul A.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351804

Subject(s) - dendrimer , supramolecular chemistry , schematic , crystallography , representation (politics) , conical surface , materials science , nanotechnology , chemistry , polymer chemistry , engineering , composite material , crystal structure , electronic engineering , politics , political science , law

Shape control : Fluorination of the n ‐dodecan‐1‐yloxy groups of the amphiphilic (3 , 4 , 5) 2 G2‐CO 2 Me monodendron changes the shape of the monodendron from an all‐ trans ‐conical to an all‐ gauche ‐crown or all‐ trans ‐tapered conformation as well as the mode of self‐assembly from a spherical to a pyramidal columnar supramolecular dendrimer (see schematic representation).

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