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Chromium( V ) and Chromium( VI ) Nitrido Complexes of Tris(pentafluorophenyl)corrole
Author(s) -
Golubkov Galina,
Gross Zeev
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351793
Subject(s) - chromium , corrole , chemistry , tris , sodium hypochlorite , manganese , hypochlorite , medicinal chemistry , ammonia , polymer chemistry , organic chemistry , biochemistry
Nitrogen‐atom transfer from a (nitrido)manganese( V ) complex to a Cr III complex of the 5,10,15‐tris(pentafluorophenyl)corrole trianion gave the stable Cr V nitrido complex 1 (Ar=C 6 F 5 ). In contrast, treatment of the same Cr III starting material with ammonia/sodium hypochlorite gave the Cr VI analogue of 1 .