Nanosized [Pd 69 (CO) 36 (PEt 3 ) 18 ]: Metal‐Core Geometry Containing a Linear Assembly of Three Face‐Sharing Centered Pd 33  Icosahedra Inside of a Hexagonal‐Shaped Pd 30  Tube | Zendy

Tran Nguyet T. | Zendy; Dahl Lawrence F. | Zendy

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Nanosized [Pd 69 (CO) 36 (PEt 3 ) 18 ]: Metal‐Core Geometry Containing a Linear Assembly of Three Face‐Sharing Centered Pd 33 Icosahedra Inside of a Hexagonal‐Shaped Pd 30 Tube

Author(s) -

Tran Nguyet T.,

Dahl Lawrence F.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351738

Subject(s) - materials science , face (sociological concept) , core (optical fiber) , crystallography , nanotechnology , geometry , chemistry , mathematics , social science , sociology , composite material

The nanosized icosahedral‐based cluster [Pd 69 (CO) 36 (PEt 3 ) 18 ] (see picture) exhibits two new salient stereochemical features: 1) a linear face‐condensation of three centered icosahedra that gives rise to a linear face‐sharing Pd 33 ‐centered triicosahedron, and 2) a hexagonal‐shaped Pd 30 tube formed by cyclic trans edge‐sharing of six Pd 7 ‐centered hexagons (host), inside of which resides the linear triicosahedron (permanent guest).

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