[3+3]Cycloalkyne Oligomers: Linking Groups Control Intra‐ and Intermolecular Aggregation by π–π Interactions | Zendy

Saiki Yuto | Zendy; Nakamura Keiichi | Zendy; Nigorikawa Yasuko | Zendy; Yamaguchi Masahiko | Zendy

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[3+3]Cycloalkyne Oligomers: Linking Groups Control Intra‐ and Intermolecular Aggregation by π–π Interactions

Author(s) -

Saiki Yuto,

Nakamura Keiichi,

Nigorikawa Yasuko,

Yamaguchi Masahiko

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351735

Subject(s) - moiety , intermolecular force , chemistry , linker , aggregate (composite) , circular dichroism , vapor pressure osmometry , molecule , polymer science , crystallography , stereochemistry , vapor pressure , organic chemistry , computer science , materials science , nanotechnology , operating system

Molecules get together : Two dimeric and a trimeric [3+3]cycloalkyne (see picture) are synthesized, and their aggregation behavior in CHCl 3 examined by 1 H NMR spectroscopy, circular dichroism, and vapor pressure osmometry. The aggregate structure of the oligomeric [3+3]cycloalkynes can be controlled by the structures of the linker moiety.

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