Rhenium‐Templated Regioselective Polyhydrogenation Reaction of [60]Fullerene | Zendy

Toganoh Motoki | Zendy; Matsuo Yutaka | Zendy; Nakamura Eiichi | Zendy

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Rhenium‐Templated Regioselective Polyhydrogenation Reaction of [60]Fullerene

Author(s) -

Toganoh Motoki,

Matsuo Yutaka,

Nakamura Eiichi

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351722

Subject(s) - regioselectivity , fullerene , rhenium , derivative (finance) , chemistry , combinatorial chemistry , nanotechnology , materials science , organic chemistry , catalysis , business , finance

Functionalizing fullerenes : The first regioselective polyhydrogenation of [60]fullerene has been achieved. Upon treatment of [60]fullerene or its derivative with 9,10‐dihydroanthracene in the presence of [Re 2 (CO) 10 ], transfer hydrometallation reaction takes place to give a polyhydrogenation product (see scheme). The reaction provided a pathway to a variety of metal η 5 complexes of hydrofullerenes.

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