A Self‐Assembled Tetracopper Triple‐Stranded Helicate: Towards the Controlled Synthesis of Finite One‐Dimensional Magnetic Chains | Zendy

Matthews Craig J. | Zendy; Onions Stuart T. | Zendy; Morata Gérald | Zendy; Davis Lisa J. | Zendy; Heath Sarah L. | Zendy; Price Daniel J. | Zendy

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A Self‐Assembled Tetracopper Triple‐Stranded Helicate: Towards the Controlled Synthesis of Finite One‐Dimensional Magnetic Chains

Author(s) -

Matthews Craig J.,

Onions Stuart T.,

Morata Gérald,

Davis Lisa J.,

Heath Sarah L.,

Price Daniel J.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351634

Subject(s) - copper , ligand (biochemistry) , self assembly , chemistry , computer science , crystallography , nanotechnology , stereochemistry , physics , materials science , receptor , biochemistry , organic chemistry

Spiraling into control : A finite linear arrangement of four magnetically coupled copper( II ) centers has been generated within a triple‐stranded helical motif that was formed through a strict self‐assembly process between a single octadentate ligand and Cu II ions (see picture). This approach opens the way to constructing finite one‐dimensional magnetic chains in a controlled manner.

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