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Rhenium–Chalcogenide–Cyano Clusters, Cu 2+ Ions, and 1,2,3,4‐Tetraaminobutane as Molecular Building Blocks for Chiral Coordination Polymers
Author(s) -
Mironov Yuri V.,
Naumov Nikolai G.,
Brylev Konstantin A.,
Efremova Olga A.,
Fedorov Vladimir E.,
Hegetschweiler Kaspar
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351595
Subject(s) - chalcogenide , rhenium , polymer , divalent , cluster (spacecraft) , crystallography , ion , chemistry , materials science , polymer chemistry , stereochemistry , inorganic chemistry , computer science , organic chemistry , programming language
Tuned to the right network : Chiral, heterometallic coordination polymers can be prepared readily by using the chiral (2S,3S)‐1,2,3,4‐butanetetramine, a labile, divalent transition‐metal cation such as Cu 2+ , and an oligonuclear, rhenium–chalcogenide–cyano cluster as starting materials (see picture).