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Toward Waste‐Free Production of Heck Products with a Catalytic Palladium System under Oxygen
Author(s) -
Dams Mieke,
De Vos Dirk E.,
Celen Sofie,
Jacobs Pierre A.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351524
Subject(s) - heck reaction , catalysis , chemistry , palladium , halide , turnover number , oxygen , oxidative coupling of methane , organic chemistry , oxidative addition
A 100 % carbon‐efficient, halide‐ and solvent‐free alternative for the synthesis of Heck‐type products is the direct oxidative coupling of arenes with olefins, catalyzed by Pd(OAc) 2 under oxygen (see scheme). The reactions can be performed under mild conditions, and water is the only by‐product. (TON=turnover number, TOF=turnover frequency.)
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